DIJ01332                             DuPontArtistri                           Page 1 of 9

July 15, 2008                                    P5000+ Series Pigment Ink

ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

MATERIAL SAFETY DATA SHEET

  1.     PRODUCT AND COMPANY IDENTIFICATION

Product Name:

ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

Product Use:

Ink-Jet Printing

Company Identification

MANUFACTURER/DISTRIBUTOR

DuPont Ink Jet and Specialty Colorants

DuPont Performance Coatings

Barley Mill Plaza

Wilmington, DE (USA)

PHONE NUMBERS

Product, Safety, Health and
Environmental Information
Transport Emergency

Medical Emergency

: 1-302-695-9682 (8 a.m.-5 p.m. ET, M-F, U.S.A)
: CHEMTREC: 1-800-424-9300 (24 hours, U.S.A)
: 1-800-441-3637 (24 hours, U.S.A.)

  1.     COMPOSITION/INFORMATION ON INGREDIENTS


Components (% by weight)

Material

CAS Number

  %

Water
Inorganic salt

Acrylic Polymer
Formaldehyde

7732-18-5

**
**

50-00-0

80-94
5-10
1-10
<0.02

Components (Remarks)

**The specific identity for each component not identified by a CAS Registry Number is withheld as a trade secret.

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ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

  1.     HAZARDS IDENTIFICATION


Potential Health Effects

THIS PRODUCT CAN BE USED SAFELY WHEN USED AS DIRECTED AND WHEN APPLICABLE SAFETY PRECAUTIONS ARE FOLLOWED.

POTENTIAL HEALTH EFFECTS FROM PRODUCT

Potential routes of overexposure to this product are skin contact, eye contact and inhalation of vapor.

Ingestion is not expected to be a significant route of exposure for this product under normal use conditions.

There is no toxicity data available for this specific formulation. Any potential hazards are presumed to be due to exposure to the components.

ADDITIONAL HEALTH EFFECTS

Since this mixture has not been tested as a whole to determine the hazards by all routes of exposure, information is provided for each hazardous component of the mixture to meet requirements of OSHA's Hazard Communication Standard (29 CFR 1910.1200). The effects noted occur from exposure to the pure component unless otherwise noted.

INFORMATION FOR COMPONENTS

INORGANIC SALT

Eye Contact - Immediate effects of overexposure may include eye irritation with tearing, pain or blurred vision.

Skin Contact - Short-term overexposure may cause irritation with itching, burning, redness, swelling or rash. Prolonged contact may cause irritation with burns or possibly

blisters.

Inhalation - Short-term overexposure may cause irritation of the nose and throat with sneezing, sore throat or runny nose.

Ingestion - Short-term overexposure may cause irritation of the digestive tract with stomach pain, heartburn, nausea, vomiting or diarrhea; however there may be no symptoms at all.

FORMALDEHYDE

Eye Contact - Can cause irritation or tearing at levels below STEL.

Skin Contact - May cause allergic skin reaction.

Inhalation - May cause respiratory disorders (sensitization). Persons with sensitive airways may react to vapors.

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July 15, 2008                                    P5000+ Series Pigment Ink

ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

Ingestion May cause throat irritation.

Carcinogenicity Information

 The following components are listed by IARC, NTP, OSHA or ACGIH as carcinogens.

Material
Formaldehyde

IARC NTP OSHA ACGIH
1 X X A2

  1.     FIRST AID MEASURES


First Aid

INHALATION

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.

SKIN CONTACT

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing. Consult a physician. Wash contaminated clothing before reuse.

EYE CONTACT

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.

Call a physician.

INGESTION

Ingestion is not an expected route of exposure during normal use of the product. If ingested, consult a physician.

  1.     FIRE FIGHTING MEASURES


Flammable Properties

Flash Point                   : >93.3  C (>200  F)

Method                      : Closed Cup

Approximate Flammable Limits in Air, % by Volume

LEL                         : Not Available

UEL                         : Not Available

Autoignition Temperature      : Not Available

Product is a nonflammable water-based solution.

DIJ01332 DuPontArtistri

July 15, 2008                         P5000+ Series Pigment Ink
ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

Hazardous combustion products (gases/vapors) produced in fire can include carbon
monoxide, carbon dioxide, nitrogen oxides and smoke.

Extinguishing Media

Use media appropriate for surrounding material.

Fire Fighting Instructions

This product is not flammable. Use normal firefighting procedures for the area.

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  1.     ACCIDENTAL RELEASE MEASURES


Safeguards (Personnel)

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Initial Containment

Dike spill.

Spill Clean Up

Soak up with absorbent material.

  1.     HANDLING AND STORAGE


Handling (Personnel)

Avoid contact with eyes, skin, or clothing.

  1.     EXPOSURE CONTROLS/PERSONAL PROTECTION


Personal Protective Equipment

EYE/FACE PROTECTION

Wear safety glasses. Wear coverall chemical splash goggles and face shield when the possibility exists for eye and face contact due to splashing or spraying of the material.

RESPIRATORS

Respirators are not needed with proper ventilation. Wear an approved respirator (e.g., an organic vapor respirator or a self-breathing apparatus whenever exposure to aerosol, mist, spray, fume or vapor exceed the exposure limit(s) of any chemical substance listed in this MSDS.

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PROTECTIVE CLOTHING

If there is potential for significant dermal contact wear appropriate impervious clothing and gloves.

Applicable Exposure Limits and Exposure Data

WATER
PEL (OSHA)
TLV (ACGIH)
AEL * (DuPont)
LD50 (rat, oral)
LC
50
(rat, inhalation/4 hr.)

: None Established
: None Established
: None Established
: >90 mL/kg (RTECS)
: No data available

INORGANIC SALT
PEL (OSHA)
TLV (ACGIH)
AEL * (DuPont)
LD
50 (rat, oral)
LD
50 (rabbit, dermal)
LC
50 (rat, inhalation/4 hr.)

: None Established
: None Established
: 7 mg/m
3, 8 & 12 Hr. TWA
: 900-2,100 mg/kg (supplier)
: >5,000 mg/kg (supplier)
: No data available

FORMALDEHYDE
STEL (OSHA)
TWA (OSHA)
ACTION LEVEL (OSHA)
STEL (ACGIH)
AEL * (DuPont)

LD50 (rat, oral)
LD
50 (rabbit, dermal)

: 2 ppm
: 0.75 ppm
: 0.5 ppm
: 0.3 ppm CEILING
: 0.5 ppm 8 and 12 Hr. TWA
: 1.0 ppm 15 minute TWA
: 100 mg/kg (supplier)
: 270 mg/kg (supplier)

* AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence.

  1.     PHYSICAL AND CHEMICAL PROPERTIES


Physical Data

Form                      : Liquid

Color                      : Clear

Odor                      : Odorless

Solubility in Water             : Miscible

pH                          : 5.9

Specific Gravity              : About 1

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Other Information

Flash Point                   : >93.3  C (>200  F)

Method                      : Closed Cup

Approximate Flammable Limits in Air, % by Volume

LEL                         : Not Available

UEL                         : Not Available

Autoignition Temperature      : Not Available

  1. STABILITY AND REACTIVITY


Chemical Stability

Stable at normal temperatures and storage conditions.

Incompatibility with Other Materials

None reasonably foreseeable.

Decomposition

Decomposition does not occur during normal use.

Polymerization

Polymerization will not occur.

  1. TOXICOLOGICAL INFORMATION


Animal Data

No data available for product.

  1. ECOLOGICAL INFORMATION


Ecotoxicological Information

No data available for product.

DIJ01332

July 15, 2008

DuPontArtistri

                        P5000+ Series Pigment Ink
ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

Page 7 of 9

  1. DISPOSAL CONSIDERATIONS


Waste Disposal

DO NOT DISCARD INTO ANY SEWERS, INTO ANY BODY OF WATER, OR ON THE GROUND. Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local laws and regulations.

  1. TRANSPORTATION INFORMATION

    (Not meant to be all inclusive)

DOT (Domestic Surface, U.S.A.)

ICAO/IATA (Air)

IMO/IMDG (Ocean)

: Not regulated

: Not regulated

: Not regulated

  1. REGULATORY INFORMATION

    (Not meant to be all inclusive - selected regulations represented)


U.S. Regulations

Federal Regulations

TSCA Inventory Status - All components of this product are listed, or exempt from listing, on the TSCA 8(b) chemical inventory.

State Regulations

State Right-To-Know

WARNING - SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM (California

Proposition 65)

Formaldehyde (50-00-0)                      < 0.02 wt. %

European Union Regulations

EU Inventory Status - All components of this product are listed, or are exempt from listing, on the EINECS chemical inventory.

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July 15, 2008                                    P5000+ Series Pigment Ink

ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

Transport Information - This product is not classified as dangerous within the meaning of transport regulations.

Labeling - This product does not need to be labeled in accordance with EC-Directive 1999/45/EC.

Switzerland

Switzerland VOC Regulations (Ordinance 814.018, Verordnung über die Lenkungsabgabe auf flüchtigen organischen Verbindungen, as of 28 December 2000)

This product is exempt from Swiss VOC regulations.

  1. OTHER INFORMATION


HMIS Rating

Health
Flammability

Reactivity

 

: 2
: 0
: 0

The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process.

MSDS Contact Information

Global Product Stewardship and Regulatory Affairs

DuPont Ink Jet and Specialty Colorants

DuPont Performance Coatings

Barley Mill Plaza

Wilmington, DE (U.S.A.)

1-302-695-9682 (U.S.A.)

Revision History

Key

July 15, 2008

New MSDS

ACGIH
AEL
Cmpds
DOT
ET
EU
HMIS

IARC
IATA
ICAO

American Conference of Governmental Industrial Hygienists
Acceptable Exposure Limit (DuPont)
Compounds
Department of Transportation (U.S.A.)
Eastern Time (U.S.A.)
European Union
Hazardous Material Information System (National Paint and Coatings
Association)
International Agency for Research on Cancer
International Air Transport Association
International Civil Aviation Organization

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July 15, 2008                                    P5000+ Series Pigment Ink

ARTISTRI P5001 PIGMENT PRETREATMENT SOLUTION

IEL                   Indicative Exposure Limit (EU Directive 2000/39/EC)

IMDG
IMO
LEL or LFL
M-F
NA
NIOSH
NOHSC

NOS
NTP
OEL
OSHA
PEL
RTECS
STEL
TLV
TSCA
TWA
UEL or UFL
U.S.A.
VOC
WEEL

International Maritime Dangerous Goods
International Maritime Organization
Lower Explosive Limit or Lower Flammable Limit
Monday through Friday
North America
National Institute of Occupational Safety and Health (U.S.A.)
National Occupational Health and Safety Commission
(Worksafe Australia)
Not Otherwise Specified
National Toxicology Program (U.S.A.)
Occupational Exposure Limit
Occupational Safety and Health Administration (U.S.A.)
Permissible Exposure Limit
Registry of Toxic Effects of Chemical Substances (NIOSH)
Short Term Exposure Limit
Threshold Limit Value
Toxic Substances Control Act (U.S.A)
Time-weighted Average
Upper Explosive Limit or Upper Flammable Limit
United States of America
Volatile Organic Compound(s)
Workplace Environmental Exposure Level

End of MSDS